▎ 摘　　要

Electrode material is a key factor for high-energy storage battery. In this paper, graphene oxide/poly(o-phenylenediamine) (GO/PoPD) hybrid composite is prepared by combining the self-assembly process to form graphene oxide/o-phenylenediamine hydrogel and subsequently the in situ oxidation polymerization, which exhibits the open porous morphology with high BET surface area of 347 m(2)/g. As the anode of lithium ion battery, GO/PoPD possesses the double lithium storage mechanisms from graphene oxide and poly(o-phenylenediamine). Meanwhile, it exhibits an initial discharge-specific capacity of 1632.4 mAh/g and the improved cycling stability. Even after 43 cycles, it still keeps a capacity of 839.5 mAh/g, which is obviously higher than that of GO and PoPD. Furthermore, GO/PoPD hybrid composite presents the enhanced rate performances with the discharge-specific capacities of 1411.7, 718.2, 621.2, and 576.3 mAh/g at current rates of 50, 100, 200, and 500 mA/g, respectively. The improved electrochemical performances are attributed to the formed stable porous morphology, which facilitates the electrolyte ion to penetrate into the electrode matrix during the redox reaction and then results in the improved cell performances.