• 文献标题:   Graphene Nanoscrolls with Confined Silicon Nanoparticles as a Durable Anode for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   WU YK, FU RS, FAN CZ, LONG ZX, SHAO GJ, LIU ZP
  • 作者关键词:   graphene nanoscroll, silicon anode, volume expansion, lithiumion batterie
  • 出版物名称:   CHEMNANOMAT
  • ISSN:   2199-692X
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   0
  • DOI:   10.1002/cnma.201900147
  • 出版年:   2019

▎ 摘  要

Silicon anodes have been given great focus due to the unparalleled theoretical specific capacity. However, destructive volume expansion during lithiation/delithiation processes and intrinsic inferior electrical conductivity cause drastic capacity decay. Forming composites with conductive and stretchable material is an effective solution to address these problems. Here, a three-dimensional continuous conductive network consisting of one-dimensional flexible graphene nanoscroll wrapped silicon nanoparticles (Si@GNS) is realized by a simple cold quenching method followed by a facile annealing process. GNS acted as conductive framework and elastic buffer layer, improving electrochemical reaction kinetics and suppressing Si volume expansion, respectively. Hence, Si@GNS shows excellent rate capability of 760 mAh g(-1) even at 2 A g(-1) and long-term cycling stability of 81.5% capacity retention after 1000 cycles.