▎ 摘　　要

The development of microfiltration (MF) membranes with a high separation flux and antifouling ability is an ultimate goal for the purification of emulsified oily wastewater by MF techniques. Herein, a dual-functional MIL-100(Fe)@graphene oxide (MIL-100(Fe)@GO) membrane is fabricated by in situ growth of MIL-100(Fe) with a graphene oxide (GO) nanosheet. The porous MIL-100(Fe)@GO composite endows the MF membrane with superhydrophilicity and demulsification functions. The MIL-100(Fe)@GO membrane achieves an outstanding water permeation flux of 12 457 L m(-2) h(-1) bar(-1), as encouraged by the versatility of MIL-100(Fe) in enabling superhydrophilicity of the MIL-100(Fe)@GO membrane and providing rich water permeation channels. An impressive emulsion separation efficiency of >99% and maximum emulsion separation flux of 5529 L m(-2) h(-1) bar(-1) are thus delivered by the MIL-100(Fe)@GO membrane. Moreover, a 131% recovery ratio of emulsion separation flux (7135 L m(-2) h(-1) bar(-1)) is attained with this system after regeneration by ethanol. In virtue of the demulsification of MIL-100(Fe), the rational design of the MIL-100(Fe) hybrid membrane exhibits a self-cleaning effect on the emulsion separation. The demonstrated high performance of the membrane system opens up new avenues for the development of membranes with antifouling abilities and ultrahigh flux for emulsion separation.