• 文献标题:   Influence of the buffer layer properties on the intensity of Raman scattering of graphene
  • 文献类型:   Article
  • 作  者:   DYAKOV SA, PEROVA TS, MIAO CQ, XIE YH, CHEREVKOV SA, BARANOV AV
  • 作者关键词:   graphene, raman spectra, enhancement of raman intensity, transfer matrix method, oscillating dipole
  • 出版物名称:   JOURNAL OF RAMAN SPECTROSCOPY
  • ISSN:   0377-0486 EI 1097-4555
  • 通讯作者地址:   Trinity Coll Dublin
  • 被引频次:   13
  • DOI:   10.1002/jrs.4294
  • 出版年:   2013

▎ 摘  要

Using a model of oscillating dipoles, we simulate the intensity of the G-band in the Raman signal from structures consisting of graphene, separated by an arbitrary buffer layer from a substrate. It is found that a structure with an optimized buffer layer refractive index and thickness exhibits a Raman signal which is nearly 50 times more intense than that from the same structure with a non-optimized buffer layer. The theoretical simulations are verified by Raman measurements on structures consisting of a layer of graphene on SiO2 and Al2O3 buffer layers. The optical contrast of the single graphene layer is calculated for an arbitrary buffer layer. It was found that both the Raman intensity and optical contrast can be maximized by varying the buffer layer thickness. Copyright (c) 2013 John Wiley & Sons, Ltd.