▎ 摘　　要

Herein, we report a melamine and metal-salt based pyrolysis technique for synthesizing metal encapsulated N-doped carbon nanotube (CNTs) in form of bamboo-like CNTs and multi walled CNTs (MWCNT). Sulfur doping during synthesis greatly influenced the physio-chemical properties of the material formed. X-ray diffraction (XRD) analysis confirms NiCo alloy (NiCo@CNT) formation that transformed into a hybrid NiCo/Co3Ni6S8/Co3O4 nanocomposite (NiCoS@CNT) in presence of sulfur. A detailed study was conducted on the mechanism of the formation of metal-encapsulated N-doped CNT structures from the polymerization of melamine. The unique NiCoS@CNT structure renders high specific surface area (232.2 m(2)/g), large pore volume (0.92 cm(2)/g), and high lattice defect with abundant oxygen vacancies resulting in excellent performance for OER and HER in alkaline medium. The hybrid catalyst requires over-potentials of 198 mV and 295 mV to deliver a current-density of 10 mAcm(-2), respectively for HER and OER. A cell voltage of only 1.53 V was required to deliver a long-term stable current-density of 10 mAcm(-2) for water splitting when NiCoS@CNT was used as both anode and cathode. Superior performance of NiCoS@CNT could be ascribed to high surface area, abundant active sites, fast charge-transfer rate, high pyridinic-N content and the presence of highly conductive CNT architecture. (C) 2020 The Author(s). Published by Elsevier Ltd.