• 文献标题:   Rodlike FeSe2-C derived from metal organic gel wrapped with reduced graphene as an anode material with excellent performance for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   YE WK, WANG K, YIN WH, CHAI WW, TANG BHJ, RUI YC
  • 作者关键词:   lithiumion batteries libs, anode, metal organic gels mogs, fese2
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Shanghai Univ Engn Sci
  • 被引频次:   4
  • DOI:   10.1016/j.electacta.2019.134817
  • 出版年:   2019

▎ 摘  要

In this work, we synthesize a high performance FeSe2-C/rGO (reduced graphene oxide) anode material for lithium-ion batteries. Benefiting from the advantages of using Fe-MOG (Metal organic gel) as precursor and the addition of rGO sheets, the rodlike FeSe2 is obtained, and the graphene not only limit the size of FeSe2 rods to smaller, but improve the conductivity. Cyclic voltammetry, galvanostatic discharge/charge and electrochemical impedance spectroscopy are utilized to examine the electrochemical characteristic of FeSe2-C/rGO anode. The cell display an extremely stable electrochemical properties during the redox reaction process and superior rate performance. Particularly, the discharge capacity of FeSe2-C/rGO anode is 917.6 mA h g(-1) after 100 cycles at 100 mA g(-1) with the coulombic efficiency of 99%, which is slightly higher than the initial discharge capacity in cycling. Besides, the FeSe2-C/rGO anode material exhibit the best cyclability compared to FeSe2-C, Fe2O3-C/rGO and FeS2-C/rGO anode material, which are prepared by the analogous synthesis process. (C) 2019 Elsevier Ltd. All rights reserved.