• 文献标题:   Low-temperature NO reduction performance of peanut shell-derived few-layer graphene loaded CeCoxMn1-xO3 catalyst
  • 文献类型:   Article, Early Access
  • 作  者:   GENG C, LI ZF, CUI JX, KANG Y, ZHANG C, LI P, YANG CL
  • 作者关键词:   psflg, cemno3, codoping, nh3scr
  • 出版物名称:   JOURNAL OF DISPERSION SCIENCE TECHNOLOGY
  • ISSN:   0193-2691 EI 1532-2351
  • 通讯作者地址:   Qiqihar Univ
  • 被引频次:   0
  • DOI:   10.1080/01932691.2020.1721008 EA JAN 2020
  • 出版年:  

▎ 摘  要

The catalysts were prepared by the hydrothermal method using agricultural waste biomass peanut shell-derived few-layer graphene (PS-FLG) as the support. The NO reduction performance test of NH3-SCR and various characterization means were employed to preliminarily explore the mechanism of Co-doping activity at the B site. The results showed that the conversion rate of NOx of the three catalysts reached 99.1% and remained stable in the range of 250 similar to 400 degrees C. The order of activity at low temperature was 5% CeCo0.5Mn0.5O3 > 5% CeMnO3 > 5% CeCoO3. Partial doping of Co could inhibit the aggregation of active components, increase the percentage of high valence ions, improve the migration of lattice oxygen (O-beta) to the adsorbed oxygen (O-alpha), and enhance the redox performance. CeCo0.5Mn0.5O3 exhibited better low-temperature activity, and the conversion rate of NOx reached 97.0% at 200 degrees C, and had excellent SO2 resistance.