• 文献标题:   Facile fabrication of molybdenum dioxide/nitrogen-doped graphene hybrid as high performance anode material for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   WANG X, XIAO Y, WANG JQ, SUN LN, CAO MH
  • 作者关键词:   molybdenum dioxide, graphene, nitrogendoping, hybrid, lithium ion batterie
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Shenzhen Univ
  • 被引频次:   35
  • DOI:   10.1016/j.jpowsour.2014.10.031
  • 出版年:   2015

▎ 摘  要

A facile, environmentally friendly and low-cost synthesis strategy is demonstrated to fabricate a MoO2/N-doped graphene (MoO2/N-GNS) hybrid, in which MoO2 nanoparticles (NPs) are uniformly dispersed on N-GNS sheets by Mo-N chemical bond formed between MoO2 and N-GNS. As an anode material in lithium ion batteries, the MoO2/N-GNS hybrid possesses superior rate capability, excellent cycling performance as well as high reversible capacity. A reversible capacity of 1138.5 mA h g(-1) is maintained after 60 cycles at a current density of 100 mA g(-1), and even at a high current density of 1000 mA g(-1), the specific capacity of 873.7 rnA h g(-1) can be obtained after 60 cycles. The superior electrochemical performance of the MoO2/N-GNS hybrid can be attributed to the synergistic effects of nitrogen-doping, flexible and conductive GNS, and MoO2 NPs. (C) 2014 Elsevier B.V. All rights reserved.