• 文献标题:   An investigation on titanium doping in reduced graphene oxide by RF magnetron sputtering for dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   LOW FW, LAI CW, ASIM N, AKHTARUZZAMAN M, ALGHOUL M, TIONG SK, AMIN N
  • 作者关键词:   dyesensitized solar cell, reduced graphene oxide, titanium dioxide, rf magnetron sputtering, doping
  • 出版物名称:   SOLAR ENERGY
  • ISSN:   0038-092X
  • 通讯作者地址:   Univ Tenaga Nas Natl Energy Univ
  • 被引频次:   6
  • DOI:   10.1016/j.solener.2019.05.069
  • 出版年:   2019

▎ 摘  要

A study investigating the effects of titanium (Ti) atoms sputtered from different sources on substrate distance was attempted in order to effectively dope a reduced graphene oxide (rGO) thin film surface. Factors such as crystallinity, morphology, phase formation, light absorption, and surface chemical state of rGO-TiO2 were investigated. As a result, functional groups or chemical states revealed the presence of Ti-O-C in rGO-TiO2 nanocomposite after the sputtering process. The titanium source from the target was of Ti3+ species as determined using X-ray photoelectron spectroscopy (XPS). It was found that average sized Ti3+ ions of around 59.4 nm were incorporated into the rGO nanosheet. A customized Dye-Sensitized Solar Cells (DSSCs) device was fabricated with the photo-anode consisting of sputtered rGO-TiO2 nanocomposite. After optimization, the Ti target allocated with 10 cm-apart FTO glass-coated rGO nanosheet and 0.67 cm(2) active area exhibited an ideal PCE of 6.60%, which is remarkably higher than the usual 5 cm sputtering distance the sample (1.90%) had achieved.