• 文献标题:   Fabrication of polyaniline/poly(ethylene oxide)/non-covalently functionalized graphene nanofibers via electrospinning
  • 文献类型:   Article
  • 作  者:   MOAYERI A, AJJI A
  • 作者关键词:   polyaniline, electrospinning, graphene, conductive polymer
  • 出版物名称:   SYNTHETIC METALS
  • ISSN:   0379-6779
  • 通讯作者地址:   Polytech Montreal
  • 被引频次:   28
  • DOI:   10.1016/j.synthmet.2014.12.020
  • 出版年:   2015

▎ 摘  要

Conducting nanofibers of polyaniline (PANi) doped with camphor-10-sulfonic acid (HCSA), blended with poly(ethylene oxide) (PEO), and filled with 1-pyrenebutanoic acid, succinimidyl ester functionalized graphene (G-PBASE) have been fabricated using electrospinning. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transforms infrared (FT-IR) and thermal gravimetric analyzer (TGA) was utilized to characterize the PANi/PEO/G-PBASE fibers morphology and properties. The observations show that electrospun fibers are highly interconnected and possess a relatively smooth surface. The average diameter of fibers was 222 +/- 60 nm. The electrical conductivity of PANi/PEO and PANi/PEO/G-PBASE at room temperature was also studied. The unique nanostructured composite of PANi/PEO/G-PBASE with small loading of G-PBASE (5 wt.% relative to PANi) showed two order of magnitude enhancement in the electrical conductivity and one order of magnitude enhancement in thermal stability in comparison to PANi/PEO nanofibers. (C)) 2014 Elsevier B.V. All rights reserved.