• 文献标题:   Graphene Sheet/Porous NiO Hybrid Film for Supercapacitor Applications
  • 文献类型:   Article
  • 作  者:   XIA XH, TU JP, MAI YJ, CHEN R, WANG XL, GU CD, ZHAO XB
  • 作者关键词:   carbon, graphene, nanostructure, nickel, supercapacitor
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   218
  • DOI:   10.1002/chem.201100727
  • 出版年:   2011

▎ 摘  要

We report the preparation of a nickel-foam-supported graphene sheet/porous NiO hybrid film by the combination of electrophoretic deposition and chemical-bath deposition. The obtained graphene-sheet film of about 19 layers was used as the nanoscale substrate for the formation of a highly porous NiO film made up of interconnected NiO flakes with a thickness of 10-20 nm. The graphene sheet/porous NiO hybrid film exhibits excellent pseudocapacitive behavior with pseudocapacitances of 400 and 324 Fg(-1) at 2 and 40 Ag(-1), respectively, which is higher than those of the porous NiO film (279 and 188 F g(-1) at 2 and 40 Ag(-1)). The enhancement of the pseudocapacitive properties is due to reinforcement of the electrochemical activity of the graphene-sheet film.