• 文献标题:   MoS2/Nitrogen-doped graphene as efficient electrocatalyst for oxygen reduction reaction
  • 文献类型:   Article
  • 作  者:   ZHAO K, GU W, ZHAO LY, ZHANG CL, PENG WD, XIAN YZ
  • 作者关键词:   nitrogendoped graphene, mos2 sheet, composite, electrocatalyst, oxygen reduction reaction
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Sch Chem Mol Engn
  • 被引频次:   42
  • DOI:   10.1016/j.electacta.2015.04.044
  • 出版年:   2015

▎ 摘  要

A simple yet effective strategy was developed to generate a non-precious oxygen electrode electrocatalyst of MoS2/nitrogen-doped graphene (NG) by physical mixing MoS2 sheets with NG. The micrometer-sized MoS2 sheets were obtained through ultrasonication exfoliation of the bulk MoS2, only showing little oxygen reduction reaction (ORR) activity. MoS2/NG hybrid was obtained by loading MoS2 sheets onto NG through ultrasonication, and the resulting nanocomposites exhibited improved electrocatalytic activity for ORR with dominant 4 electron pathway in alkaline solutions. The exposed active edges as well as the synergistic effect and reduced resistance connection jointly make the MoS2/NG composite a highly competitive ORR catalyst. (C) 2015 Elsevier Ltd. All rights reserved.