• 文献标题:   Enhanced performance of Li-S battery with polymer doped potassium functionalized graphene interlayers as effective polysulfide barrier
  • 文献类型:   Article
  • 作  者:   KIAI MS, KIZIL H
  • 作者关键词:   lis battery, graphene nanoplate, polymer dopant, capacity retention, polysulfide
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Istanbul Tech Univ
  • 被引频次:   2
  • DOI:   10.1016/j.jelechem.2019.113405
  • 出版年:   2019

▎ 摘  要

In this study, the electrochemical performances of the novel glass fiber separators coated with potassium functionalized graphene (K-FGF) doped with polyaniline (PANI), poly 1,5-diaminoanthraquinone (PDAAQ) and PDAAQ/multi wall carbon nanotubes (MWCNT)/cetyltrimethyl-ammoniurn-bromide (CTAB) were evaluated for their ability of polysulfide entrapment to improve the cycling stability and the capacity fading rate. The test results showed that K-FGF coated glass fiber separator doped with PDAAQ and PDAAQ/MWCNT/CTAB displayed incredible improvement in the electrochemical performance of the battery, with high initial capacity of 1346 and 1361 mAh g(-1) and capacity retention of 804 and 968 mAh g(-1) after 200 cycles respectively. It is evident that PDAAQ suppresses the polysulfides shuttle in the electrolyte and offers a strong binding energy for the adsorption of polysulfides on the separator surface. (C) 2019 Elsevier B.V. All rights reserved.