• 文献标题:   Electrochemical determination of sulfide in fruits using alizarin-reduced graphene oxide nanosheets modified electrode
  • 文献类型:   Article
  • 作  者:   CAO XD, XU HC, DING S, YE YK, GE XG, YU L
  • 作者关键词:   sulfide, reduced graphene oxide nanosheet, alizarin, electrochemical detection
  • 出版物名称:   FOOD CHEMISTRY
  • ISSN:   0308-8146 EI 1873-7072
  • 通讯作者地址:   Hefei Univ Technol
  • 被引频次:   23
  • DOI:   10.1016/j.foodchem.2015.08.134
  • 出版年:   2016

▎ 摘  要

This study presents a new approach for rapid detection of sulfide using a glassy carbon electrode (GCE) modified with alizarin (Az) and reduced graphene oxide (rGO) nanosheets. The fabricate Az-rGO/GCE sensor shows a notable electrocatalytic activity to sulfide oxidation. The currents of anodic peak centered at +465 mV in 0.2 M pH 7.0 phosphate buffer were related linearly to the concentrations of sulfide, based on the cyclic voltammetric studies. The linear range was 0.002-3.28 mM, and the detection limit was 1 mu M. The proposed method was applied in sulfide determination of hydrogen sulfide pretreated fruits, and the method was also verified with recovery studies. (C) 2015 Elsevier Ltd. All rights reserved.