• 文献标题:   Microwave-assisted synthesis of Co3O4-graphene sheet-on-sheet nanocomposites and electrochemical performances for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   SU QM, YUAN WW, YAO LB, WU YS, ZHANG J, DU GH
  • 作者关键词:   nanostructure, composite, electron microscopy, electrochemical propertie
  • 出版物名称:   MATERIALS RESEARCH BULLETIN
  • ISSN:   0025-5408 EI 1873-4227
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   22
  • DOI:   10.1016/j.materresbull.2015.07.035
  • 出版年:   2015

▎ 摘  要

Porous Co3O4 nanosheets anchored on graphene nanosheets were synthesized by microwave irradiation method. The obtained Co3O4-graphene sheet-on-sheet nanocomposite as an anode material for LIBs demonstrates a high initial discharge capacity of 1359.6 mAhg(-1) with a Columbic efficiency of 72.7% at a rate of 100 mA g(-1). Moreover, a significantly enhanced reversible capacity of similar to 1036.9 mAh g(-1) is retained after 50 cycles, and the capacity can reincrease to 1068 mAh g(-1) when the current density returns back to 100 mA g(-1) after cycled at various rates for 50 cycles. The improved electrochemical performance is attributed to the unique architectures of the porous Co3O4 nanosheets and the incorporation of graphene nanosheets. Therefore, this nanocomposite is widely considered to be an attractive candidate as an anode material for next-generation LIBs. (C) 2015 Elsevier Ltd. All rights reserved.