• 文献标题:   Incorporation of Manganese Dioxide within Ultraporous Activated Graphene for High-Performance Electrochemical Capacitors
  • 文献类型:   Article
  • 作  者:   ZHAO X, ZHANG LL, MURALI S, STOLLER MD, ZHANG QH, ZHU YW, RUOFF RS
  • 作者关键词:   amego, mno2, composite, asymmetric, electrochemical capacitor
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Univ Sci Technol China
  • 被引频次:   273
  • DOI:   10.1021/nn3012916
  • 出版年:   2012

▎ 摘  要

Manganese dioxide (MnO2) particles 2-3 nm in size were deposited onto a porous "activated microwave expanded graphite oxide" (aMEGO) carbon scaffold via a self-controlled redox process. Symmetric electrochemical capacitors were fabricated that yielded a specific capacitance of 256 F/g (volumetric: 640 F/cm(3)) and a capacitance retention of 87.7% after 1000 cycles in 1 M H2SO4; when normalized to MnO2, the specific capacitance was 850 F/g. Asymmetric electrochemical capacitors were also fabricated with aMEGO/MnO2 as the positive electrode and aMEGO as the negative electrode and had a power density of 32.3 kW/kg (for an energy density of 20.8 Wh/kg), an energy density of 24.3 Wh/kg (for a power density of 24.5 kW/kg), and a capacitance retention of 80.5% over 5000 cycles.