• 文献标题:   In Situ Synthesis of FeSn2/Graphene Nanocomposite via One-Pot Solvothermal Route and Its Electrochemical Li-Storage Properties
  • 文献类型:   Article
  • 作  者:   FENG B, XIE J, CAO GS, ZHU TJ, ZHAO XB
  • 作者关键词:   graphene, fesn2, nanocomposite, anode material, electrochemical performance
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   8
  • DOI:  
  • 出版年:   2012

▎ 摘  要

In this work, a FeSn2/graphene nanocomposite was synthesized by a facile in situ one-pot solvothermal route. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Raman spectra (RS) results indicated that the formation of FeSn2 and the reduction of graphite oxide (GO) to graphene occur simultaneously during the one-pot solvothermal process. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observations showed that the quasi-spheric FeSn2 particles with a size of 10-30 nm are uniformly anchored on graphene. The electrochemical Li-storage performance of the nanocomposite was investigated by galvanostatic cycling. The nanocomposite exhibits an obvious improved electrochemical performance compared to bare FeSn2. The enhancement of the electrochemical performance could be attributed to the introduction of graphene that not only constructs two-dimensional conductive networks but also disperses and confines the FeSn2 nanoparticles.