• 文献标题:   Sustainable synthesis of cellulose-derived magnetic iron oxide/sulfonated graphene oxide-like material from corncob for conversion of hemicellulose to furfural
  • 文献类型:   Article
  • 作  者:   TINH NT, DAN DK, PHUONG NT, DAT NM, KHANG PT, BAO PP, BAO LM, NHAN DD, KHOA NN, HANH NT, HOA DN, VIET VND, DANH TT, CHAU PTL, PHONG MT, HIEU NH
  • 作者关键词:   magnetic iron oxide, sulfonated graphene, oxidelike catalyst, corncob, furfural
  • 出版物名称:   FUEL
  • ISSN:   0016-2361 EI 1873-7153
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.fuel.2023.127870 EA FEB 2023
  • 出版年:   2023

▎ 摘  要

Developing a method to convert biomass sources into valuable products has always been a matter of great in-terest to many researchers. In this work, a cellulose-derived magnetic iron oxide/sulfonated graphene oxide-like (Cel-MSGO) material was synthesized from corncob by sulfonation and hydrothermal processing, in order to catalyze the conversion of hemicellulose to furfural. Characteristics of the as-synthesized Cel-MSGO were investigated using modern analytical methods. Scanning electron microscopy revealed that Fe3O4 particles were attached to the surface of sheets structurally similar to sulfonated graphene oxide. The sheet-like structure of the obtained Cel-MSGO was also observed from high-resolution transmission electron microscopy as similar to that of graphene oxide. The Cel-MSGO material was investigated for its ability to convert hemicellulose of corncob into furfural through the following factors: reaction temperature, reaction time, amount of catalyst, and solvent ratio H2O:gamma-valerolactone (H2O:GVL). The Cel-MSGO material showed excellent catalysis with a furfural yield of 55.05%, xylose conversion of 97.80%, and furfural selectivity of 57.20% under reaction conditions of 190 degrees C, a reaction time of 150 min, and a catalyst amount of 10 wt% in a solvent system consisting 80:20 H2O:GVL (v/v). Furthermore, the catalyst showed good reusability after 6 cycles. This study opens a new application direction in utilizing biomass to synthesize high-value products, contributing to reducing environmental pollution and solving the situation of exhausted renewable raw materials.