• 文献标题:   The effect of the temperature of graphene oxide reduction on low- temperature sorption of He-4
  • 文献类型:   Article
  • 作  者:   DOLBIN AV, KHLISTYUCK MV, ESEL SON VB, GAVRILKO VG, VINNIKOV NA, BASNUKAEVA RM, MALUENDA I, MASER WK, BENITO AM
  • 作者关键词:  
  • 出版物名称:   LOW TEMPERATURE PHYSICS
  • ISSN:   1063-777X EI 1090-6517
  • 通讯作者地址:   Natl Acad Sci Ukraine
  • 被引频次:   1
  • DOI:   10.1063/1.4939155
  • 出版年:   2016

▎ 摘  要

The sorption of He-4 by graphene oxide powders thermally reduced at T = 200, 300, 500, 700, 900 degrees C has been investigated in the interval 1.5-290 K. The measured dependence of the quantity of sorbed helium upon the reduction temperature shows up as a nonmonotonic curve. The highest quantities of helium were sorbed by the samples reduced at T = 300 and 900 degrees C. It is assumed that the thermal reduction of graphite oxide by heating it to 300 degrees C causes evaporation of the water intercalated in the spacings of the carbon layers, this results in exfoliation of the graphene planes, which enhances the sorptive capacity. Heating the samples to 900 degrees C generates numerous defects in the carbon planes, as a result, the interlayer spacings become accessible for sorption, which enhances the sorptive capacity. (C) 2016 AIP Publishing LLC.