▎ 摘　　要

Advanced fabric with ordered structures, unimpeded ionic channels, and high mechanical flexibility are profoundly significant for wearable supercapacitors. However, the restacking structure and weakened porosity, both of which block ionic kinetic migration and surface accessibility, result in low energy density. Here, we develop a hierarchical porous graphene fibers-assembled fabric (HP-GFF) for high-performance supercapacitors. By precisely manipulating the microfluidic assembly and chemical etching processes, the HP-GFF maintains open interlinkage porous backbone, ordered pathways, large accessible surface (221 m2/g), high mechanical flexibility (elongation: 197%) and large production size (30 x 20 cm), which also help in facilitating electrolyte ions migration and intercalation. The resulting HP-GFF displays a large capacitance of 312.9F/g (1248.5 mF/cm2) and ultrahigh stability (60000 cycles) in H2SO4 electrolyte. Furthermore, the HP-GFF-constructed solid-state flexible supercapacitor also delivers high energy density (120.2 mu Wh/cm2), excellent capacitance, and washable/ deformable capabilities, which are remarkably demonstrated in actually wearable and self-powered applications such as a toy boat, electrical fan and smart watch.