• 文献标题:   Design and synthesis of graphene/SnO2/polyacrylamide nanocomposites as anode material for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   WAN YX, WANG TY, LU HY, XU XQ, ZUO C, WANG Y, TENG C
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Peking Univ
  • 被引频次:   1
  • DOI:   10.1039/c8ra00958a
  • 出版年:   2018

▎ 摘  要

Tin dioxide (SnO2) is a promising anode material for lithium-ion batteries owing to its large theoretical capacity (1494 mA h g(-1)). However, its practical application is hindered by these problems: the low conductivity, which restricts rate performance of the electrode, and the drastic volume change (400%). In this study, we designed a novel polyacrylamide/SnO2 nanocrystals/graphene gel (PAAm@SnO2NC@GG) structure, in which SnO2 nanocrystals anchored in three-dimensional graphene gel network and the polyacrylamide layers could effectively prevent the agglomeration of SnO2 nanocrystals, presenting excellent cyclability and rate performance. A capacity retention of over 90% after 300 cycles of 376 mA h g(-1) was achieved at a current density of 5 A g(-1). In addition, a stable capacity of about 989 mA h g(-1) at lower current density of 0.2 A g(-1) was achieved.