• 文献标题:   Functionalized Graphene and Carbon Materials as Additives for Melt-Extruded Flame Retardant Polypropylene
  • 文献类型:   Article
  • 作  者:   HOFMANN D, WARTIG KA, THOMANN R, DITTRICH B, SCHARTEL B, MULHAUPT R
  • 作者关键词:   extrusion, flame retardance, graphene, nanocomposite, polypropylene
  • 出版物名称:   MACROMOLECULAR MATERIALS ENGINEERING
  • ISSN:   1438-7492 EI 1439-2054
  • 通讯作者地址:   Univ Freiburg
  • 被引频次:   38
  • DOI:   10.1002/mame.201200433
  • 出版年:   2013

▎ 摘  要

Functionalized graphene nanosheets TRGO and MLG 250, prepared from thermally reduced graphite oxide, represent attractive carbon additives for improving the performance of flame retardant polypropylene (PP-FR). The influence of carbon nanofiller type and content on morphology, thermal, mechanical, and electrical properties as well as the fire behavior of melt-extruded PP-FR is investigated. In contrast to conventional nano- and micron-sized carbon fillers such as expanded graphite (EG 40), nano-scaled carbon black (CB), and multiwall carbon nanotubes (CNT), only TRGO and MLG 250 afford uniform dispersion combined with simultaneously improved stiffness (+80%), electrical conductivity (3x10(-5) Scm(-1)) and enhanced flame retardancy of PP-FR, as expressed by lower peak heat release rate (-76%).