• 文献标题:   Hierarchical Nanocomposites of Polyaniline Nanowire Arrays on Graphene Oxide Sheets with Synergistic Effect for Energy Storage
  • 文献类型:   Article
  • 作  者:   XU JJ, WANG K, ZU SZ, HAN BH, WEI ZX
  • 作者关键词:   hierarchical, nanocomposite, conducting polymer, graphene oxide, supercapacitor
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Natl Ctr Nanosci Technol
  • 被引频次:   959
  • DOI:   10.1021/nn1006539
  • 出版年:   2010

▎ 摘  要

We introduced a facile method to construct hierarchical nanocomposites by combining one-dimensional (1D) conducting polyaniline (PANI) nanowires with 2D graphene oxide (GO) nanosheets. PANI nanowire arrays are aligned vertically on GO substrate. The morphologies of PANI nanowires can be controlled by adjusting the ratios of aniline to GO, which are attributed to different nucleation processes. The hierarchical nanocomposite structures of PANI GO were further proved by UV-vis, FTIR, and XRD measurements. The hierarchical nanocomposite possessed higher electrochemical capacitance and better stability than each individual component as supercapacitor electrode materials, showing a synergistic effect of PANI and GO. This study will further guide the preparation of functional nanocomposites by combining different dimensional nanomaterials.