• 文献标题:   SERS Sensing Properties of New Graphene/Gold Nanocomposite
  • 文献类型:   Article
  • 作  者:   NERI G, FAZIO E, MINEO PG, SCALA A, PIPERNO A
  • 作者关键词:   graphene/gold nanocomposite, sers, dopamine, rhodamine 6g
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:   Univ Messina
  • 被引频次:   7
  • DOI:   10.3390/nano9091236
  • 出版年:   2019

▎ 摘  要

The development of graphene (G) substrates without damage on the sp(2) network allows to tune the interactions with plasmonic noble metal surfaces to finally enhance surface enhanced Raman spectroscopy (SERS) effect. Here, we describe a new graphene/gold nanocomposite obtained by loading gold nanoparticles (Au NPs), produced by pulsed laser ablation in liquids (PLAL), on a new nitrogen-doped graphene platform (G-NH2). The graphene platform was synthesized by direct delamination and chemical functionalization of graphite flakes with 4-methyl-2-p-nitrophenyl oxazolone, followed by reduction of p-nitrophenyl groups. Finally, the G-NH2/Au SERS platform was prepared by using the conventional aerography spraying technique. SERS properties of G-NH2/Au were tested using Rhodamine 6G (Rh6G) and Dopamine (DA) as molecular probes. Raman features of Rh6G and DA are still detectable for concentration values down to 1 x 10(-5) M and 1 x 10(-6) M respectively.