• 文献标题:   Enhanced activity and stability of Pt catalysts on functionalized graphene sheets for electrocatalytic oxygen reduction
  • 文献类型:   Article
  • 作  者:   KOU R, SHAO YY, WANG DH, ENGELHARD MH, KWAK JH, WANG J, VISWANATHAN VV, WANG CM, LIN YH, WANG Y, AKSAY IA, LIU J
  • 作者关键词:   functionalized graphene sheet, fuel cell, pt, cathode durability
  • 出版物名称:   ELECTROCHEMISTRY COMMUNICATIONS
  • ISSN:   1388-2481 EI 1873-1902
  • 通讯作者地址:   Pacific NW Natl Lab
  • 被引频次:   467
  • DOI:   10.1016/j.elecom.2009.02.033
  • 出版年:   2009

▎ 摘  要

Electrocatalysis of oxygen reduction using Pt nanoparticles supported on functionalized graphene sheets (FGSs) was studied. FGSs were prepared by thermal expansion of graphite oxide. Pt nanoparticles with average diameter of 2 nm were uniformly loaded on FGSs by impregnation methods. Pt-FGS showed a higher electrochemical surface area and oxygen reduction activity with improved stability as compared with the commercial catalyst. Transmission electron microscopy, X-ray photoelectron spectroscopy, and electrochemical characterization suggest that the improved performance of Pt-FGS can be attributed to smaller particle size and less aggregation of Pt nanoparticles on the functionalized graphene sheets. Published by Elsevier B.V.