• 文献标题:   Embedded Si/Graphene Composite Fabricated by Magnesium-Thermal Reduction as Anode Material for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   ZHU JL, REN YR, YANG B, CHEN WK, DING JN
  • 作者关键词:   embedded si/graphene composite, magnesiumthermal reduction, anode material
  • 出版物名称:   NANOSCALE RESEARCH LETTERS
  • ISSN:   1556-276X
  • 通讯作者地址:   Changzhou Univ
  • 被引频次:   5
  • DOI:   10.1186/s11671-017-2400-6
  • 出版年:   2017

▎ 摘  要

Embedded Si/graphene composite was fabricated by a novel method, which was in situ generated SiO2 particles on graphene sheets followed by magnesium-thermal reduction. The tetraethyl orthosilicate (TEOS) and flake graphite was used as original materials. On the one hand, the unique structure of as-obtained composite accommodated the large volume change to some extent. Simultaneously, it enhanced electronic conductivity during Li-ion insertion/extraction. The MR-Si/G composite is used as the anode material for lithium ion batteries, which shows high reversible capacity and ascendant cycling stability reach to 950 mAh.g(-1) at a current density of 50 mA.g(-1) after 60 cycles. These may be conducive to the further advancement of Si-based composite anode design.