• 文献标题:   Fabrication of Polyaniline/Graphene/Polyester Textile Electrode Materials for Flexible Supercapacitors with High Capacitance and Cycling Stability
  • 文献类型:   Article
  • 作  者:   SHAO F, BIAN SW, ZHU Q, GUO MX, LIU S, PENG YH
  • 作者关键词:   electrochemistry, graphene, nanowire, polymerization, supercapacitor
  • 出版物名称:   CHEMISTRYAN ASIAN JOURNAL
  • ISSN:   1861-4728 EI 1861-471X
  • 通讯作者地址:   Donghua Univ
  • 被引频次:   21
  • DOI:   10.1002/asia.201600411
  • 出版年:   2016

▎ 摘  要

Vertical polyaniline (PANI) nanowire arrays on graphene-sheet-coated polyester cloth (RGO/PETC) were fabricated by the insitu chemical polymerization of aniline. The 3D conductive network that was formed by the graphene sheets greatly enhanced the conductivity of PANI/RGO/PETC and improved its mechanical stability. PANI nanowire arrays increased the active surface area of PANI, whilst the hierarchically porous structure of the PANI/RGO/PETC electrode facilitated the diffusion of the electrolyte ions. Electrochemical measurements showed that the composite electrode exhibited a maximum specific capacitance of 1293Fg(-1) at a current density of 1Ag(-1). Capacitance retention was greater than 95%, even after 3000cycles, which indicated that the electrode material has excellent cycling stability. Moreover, the electrode structure endowed the PANI/RGO/PETC electrode with a stable electrochemical performance under mechanical bending and stretching.