• 文献标题:   Growth of nickel (111) plane: The key role in nickel for further improving the electrochemical property of hexagonal nickel hydroxide-nickel & reduced graphene oxide composite
  • 文献类型:   Article
  • 作  者:   ZHANG JL, LIU HD, SHI P, LI YJ, HUANG LH, MAI WJ, TAN SZ, CAI X
  • 作者关键词:   reduced graphene oxide, nickel hydroxide, nickel, plane, supercapacitor
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Jinan Univ
  • 被引频次:   31
  • DOI:   10.1016/j.jpowsour.2014.05.106
  • 出版年:   2014

▎ 摘  要

Hexagonal nickel hydroxide/nickel decorated on reduced graphene oxide (rGO&Ni(OH)(2)-Ni) has been prepared via easy one-step chemical precipitation method and subsequent annealing treatment. The results show that the thermal stability of Ni(OH)(2) is enhanced by the incorporation of Ni. Besides, hexagonal Ni(OH)(2) Ni nanoplate which can supply a short diffusion and migration pathway for electron and electrolyte ion contacts closely with the surface of rGO, resulting that the agglomeration of rGO is effectively prevented. Due to the good electrical conductivity of Ni, the incorporation of Ni can also improve the electrical conductivity of Ni(OH)(2). More importantly, the Ni (111) plane is grown after annealing treatment, which plays a key role in Ni for further improving the electrochemical activity of composite. Consequently, the rGO&Ni(OH)(2) Ni electrode exhibits high capacitance, high energy density, excellent rate capability, good cycle stability, etc. The advantages of easy preparation and excellent electrochemical performance imply the great potential application of rGO&Ni(OH)(2) Ni in supercapacitors. Moreover, it is worthy noting that this work will offer a new approach for using metal nanoparticle in improving the electrochemical property of supercapacitor electrode material. Crown Copyright (C) 2014 Published by Elsevier B.V. All rights reserved.