• 文献标题:   Improving Li reversibility in Li metal batteries through uniform dispersion of Ag nanoparticles on graphene
  • 文献类型:   Article
  • 作  者:   GAO Y, CUI BF, WANG JJ, SUN ZY, CHEN Q, DENG YD, HAN XP, HU WB
  • 作者关键词:   ag/graphene composite, uniform li deposition, li anode, li metal batterie
  • 出版物名称:   RARE METALS
  • ISSN:   1001-0521 EI 1867-7185
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1007/s12598-022-02044-8 EA AUG 2022
  • 出版年:   2022

▎ 摘  要

Li metal is the most attractive and promising anode material for next-generation high-energy batteries. However, uncontrolled Li dendrite growth during cycling remains a highly challenging drawback. To solve this problem, silver-coated graphene (Ag/GH) was prepared via a simple liquid-phase reduction method. The effect of Ag/GH on Li deposition behavior was investigated by adjusting the dispersion of Ag nanoparticles (Ag NPs). Subsequently, a composite electrode was fabricated via uniform deposition of metallic Li on Ag/GH. Ag was used as a lithiophilic nucleating agent to ensure uniform deposition of Li and inhibit the growth of Li dendrites on the anode. The prepared composite anode showed a significantly improved performance compared to the unmodified electrode. The symmetric cell comprising this composite electrode exhibited a stable cycling performance with a low hysteresis of similar to 40 mV and a lifetime of > 2000 h at a current density of 0.5 mA.cm(-2). Meanwhile, the discharge capacity reached 0.5 mAh.cm(-2). In addition, Ag/GH was found to be amenable to large-scale synthesis. Thus, the composite Ag/GH anode exhibited improved performance and the preparation method showed significant potential for application in the manufacture of Li metal batteries.