• 文献标题:   Sensing hydrogen peroxide using a glassy carbon electrode modified with in-situ electrodeposited platinum-gold bimetallic nanoclusters on a graphene surface
  • 文献类型:   Article
  • 作  者:   CUI X, WU SN, LI YX, WAN G
  • 作者关键词:   ptau bimetallic nanocluster, graphene, hydrogen peroxide, electrochemical sensor
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Anhui Normal Univ
  • 被引频次:   33
  • DOI:   10.1007/s00604-014-1321-7
  • 出版年:   2015

▎ 摘  要

Platinum-gold nanoclusters (PtAu NCs) were electrodeposited on graphene placed on the surface of a glassy carbon electrode (GCE). The PtAu-graphene nanocomposite was characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, and electrochemical methods. The PtAu NCs display excellent electrocatalytic activity towards the reduction of hydrogen peroxide. This effect was exploited in a sensor that responds (at a working voltage of 100 mV) to H2O2 in the 15 nM to 8.73 mu M concentration range, with a limit of detection at 8.0 nM.