• 文献标题:   Graphene/Polyaniline Nanocomposite for Hydrogen Sensing
  • 文献类型:   Article
  • 作  者:   ALMASHAT L, SHIN K, KALANTARZADEH K, PLESSIS JD, HAN SH, KOJIMA RW, KANER RB, LI D, GOU XL, IPPOLITO SJ, WLODARSKI W
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   RMIT Univ
  • 被引频次:   311
  • DOI:   10.1021/jp103134u
  • 出版年:   2010

▎ 摘  要

Here we report on the synthesis of a graphene/polyaniline (PANI) nanocomposite and its application in the development of a hydrogen (H(2)) gas sensor. Using a chemical synthetic route, graphene was prepared and ultrasonicated with a mixture of aniline monomer and ammonium persulfate to form PANI on its surface. The developed material was characterized by scanning electron microscopy (SEM), transmission electron microscopy, Raman spectroscopy, and X-ray photoemission spectroscopy. The SEM study revealed that the PANI in the composite has a nanofibrillar morphology. We investigated the H(2) gas sensing performance of this material and compare it with that of the sensors based on only graphene sheets and PANI nanofibers. We found that the graphene/PANI nanocomposite-based device sensitivity is 16.57% toward 1% of H(2) gas, which is much larger than the sensitivities of sensors based on only graphene sheets and PANI nanofibers.