• 文献标题:   PHOTOELECTRIC CONVERSION PERFORMANCE OF WATER-SOLUBLE PALLADIUM-PORPHYRIN/GRAPHENE OXIDE NONCOVALENT COMPOSITES
  • 文献类型:   Article
  • 作  者:   WANG YT, WU RR, ZHANG YY, WANG BH, LEE HW
  • 作者关键词:   graphene oxide, pdtrimethylammonium tetraphenyl porphyrin, photoelectric conversion performance, phosphor, noncovalent interaction
  • 出版物名称:   JOURNAL OF APPLIED SPECTROSCOPY
  • ISSN:   0021-9037 EI 1573-8647
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1007/s10812-023-01492-z EA JAN 2023
  • 出版年:   2023

▎ 摘  要

We synthesize a phosphor by combining trimethylammonium tetraphenyl porphyrin with palladium (II), obtaining Pd-TTAP, and investigate its interaction with graphene oxide (GO). Pd-TTAP and GO are found to be noncovalently bonded, according to high-resolution transmission electron microscopy (HR-TEM), ultraviolet-visible spectroscopy (UV-Vis), room temperature phosphorescence spectroscopy (RTP), Raman spectroscopy, and infrared spectroscopy (IR). The binding constant is 2.32 x 10(4) M-1, calculated using the Benesi-Hildebrand method, and a photoelectric response test finds that photo-induced electrons are transferred from the triplet excited state of Pd-TTAP to GO under visible light excitation. Our results demonstrate that Pd-TTAP can serve as an eff ective energy donor, with GO as an electron acceptor, in photoelectric conversion systems.