• 文献标题:   Supercapacitive performance of porous graphene nanosheets in bis(trifluoromethylsulfony)imide and bis(fluorosulfonyl)imide ionic liquid electrolytes
  • 文献类型:   Article
  • 作  者:   PAN BR, LEE SW, TSENG CJ, CHANG CL, HUNG WC, CHANG JK
  • 作者关键词:   supercapacitor, porous structure, graphene electrode, ionic liquid
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Natl Cent Univ
  • 被引频次:   3
  • DOI:   10.1007/s10008-018-3926-y
  • 出版年:   2018

▎ 摘  要

A method of high-heating-rate thermal reduction is used to produce porous graphene nanosheets (PGNSs). This material is characterized by a unique holey structure, which is suitable for ionic liquid (IL) electrolyte. To study the effects of electrolyte anion, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfony)imide (EMI-TFSI) and 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide (EMI-FSI) ILs are used. Due to the smaller size of FSI-, EMI-FSI shows a higher conductivity and lower viscosity than those of EMI-TFSI. The specific capacitances of PGNS electrodes are 90 and 260 F g(-1), respectively, measured in EMI-TFSI and EMI-FSI ILs at a potential scan rate of 50 mV s(-1). The PGNS symmetric cell with EMI-FSI electrolyte is able to deliver a maximum energy and power densities of 110 Wh kg(-1) and 101 kW kg(-1), respectively, with a cell voltage of 3.5 V. In addition, 85% of the initial capacity can be retained after 2000 charge-discharge cycles.