• 文献标题:   Platinum nanoparticles on carbon nanomaterials with graphene structure as hydrogenation catalysts
  • 文献类型:   Article
  • 作  者:   KUSHCH SD, KUJUNKO NS, TARASOV BP
  • 作者关键词:  
  • 出版物名称:   RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  • ISSN:   1070-3632 EI 1608-3350
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   13
  • DOI:   10.1134/S1070363209040057
  • 出版年:   2009

▎ 摘  要

Carbon nanomaterials with graphene structure (single- and multiwall nanotubes and nanofibers) after oxidizing by a mixture of sulfuric and nitric acids and presumable introducing of carboxyl groups can be used as carrying agents of hydrogenation catalysts. Platinum in a concentration which should not exceed 10 wt % can be fixed using H2PtCl6 as a precursor in presence of an organic base. Catalysts based on these nanomaterials with the average size of platinum particles 6-8 nm exceed in activity the Pt/C catalyst with the size of platinum particles 65-70 nm, but are inferior to catalysts based on fullerene black with the average size of platinum particles 3-4 nm.