• 文献标题:   A composite film of reduced graphene oxide modified vanadium oxide nanoribbons as a free standing cathode material for rechargeable lithium batteries
  • 文献类型:   Article
  • 作  者:   SUN Y, YANG SB, LV LP, LIEBERWIRTH I, ZHANG LC, DING CX, CHEN CH
  • 作者关键词:   vanadium oxide, graphene, nanoribbon, cathode, lithium battery
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Univ Sci Technol China
  • 被引频次:   38
  • DOI:   10.1016/j.jpowsour.2013.04.093
  • 出版年:   2013

▎ 摘  要

Hydrated vanadium pentoxide (V2O5 center dot 0.86H(2)O) nanoribbons modified with reduced graphene oxide (RGO) are synthesized by a hydrothermal process. These ribbons are 30 nm thick, 200 nm to 1 mu m wide and above 50 mu m long. Binder-free films are prepared by using these ribbons and annealed at 300 degrees C in nitrogen as the cathode for rechargeable lithium cells. The intertwining network of this free-standing VOx/RGO film provides efficient conduction pathways for electrons and short diffusion distances for Li ions. The electrochemical tests exhibit that this cathode film delivers a high reversible specific capacity (160 mAh g(-1)) and good cycling stability (133 mAh g(-1) after 200 cycles) in the voltage range between 2.0 and 3.5 V. (C) 2013 Elsevier B.V. All rights reserved.