• 文献标题:   Reduced chemically modified graphene oxide for supercapacitor electrode
  • 文献类型:   Article
  • 作  者:   RAJAGOPALAN B, CHUNG JS
  • 作者关键词:   graphene oxide, chemical reduction, active material, supercapacitor
  • 出版物名称:   NANOSCALE RESEARCH LETTERS
  • ISSN:   1931-7573 EI 1556-276X
  • 通讯作者地址:   Univ Ulsan
  • 被引频次:   49
  • DOI:   10.1186/1556-276X-9-535
  • 出版年:   2014

▎ 摘  要

An efficient active material for supercapacitor electrodes is prepared by reacting potassium hydroxide (KOH) with graphene oxide followed by chemical reduction with hydrazine. The electrochemical performance of KOH treated graphene oxide reduced for 24 h (reduced chemically modified graphene oxide, RCMGO-24) exhibits a specific capacitance of 253 F g(-1) at 0.2 A g(-1) in 2 M H2SO4 compared to a value of 141 F g(-1) for graphene oxide reduced for 24 h (RGO-24), and good cyclic stability up to 3,000 cycles. Interestingly, RCMGO-24 demonstrated a higher specific capacitance and excellent cycle stability due to its residual oxygen functional groups that accelerate the faradaic reactions and aid in faster wetting. This non-annealed strategy offers the potential for simple and cost-effective preparation of an active material for a supercapacitor electrode.