• 文献标题:   Rational design of Spirulina residue-derived graphene oxide as an efficient metal-free catalyst for sulfathiazole removal
  • 文献类型:   Article
  • 作  者:   WANG K, ZHANG SY, WANG RP, LIU YL, CAO GL, DUAN XG, HO SH
  • 作者关键词:   spirulina residue, graphene oxide, peroxymonosulfate, sulfamethoxazole, nonradical reaction
  • 出版物名称:   SEPARATION PURIFICATION TECHNOLOGY
  • ISSN:   1383-5866 EI 1873-3794
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.1016/j.seppur.2022.120862 EA MAR 2022
  • 出版年:   2022

▎ 摘  要

Advanced oxidation processes (AOPs) based on peroxymonosulfate (PMS) activation has attracted extensive attention in wastewater remediation. Although traditional transition metal or metal oxide-based catalysts exhibit high efficiency in PMS activation, they inevitably suffer from metal leaching. Herein, the Spirulina residue graphene oxide (SRGO) was synthesized as a bio-GO to effectively activate PMS to degrade sulfathiazole (STZ). After analysis, the performance of SRGO was highly-related to salinity, and the removal rate of STZ via high salinity group named as SRGO-HS/PMS system was as high as 100% within 10 min. Moreover, the excellent and stable regeneration of SRGO-HS (>83%) was verified through four consecutive recycling. Notably, electron spin resonance (ESR), electrochemical and quenching experiments clearly indicated that the degradation of STZ in SRGO-HS/PMS was mainly occurred by the non-radical reactions based on singlet oxygen (O-1(2)) and electron transfer, suggesting its high sustainability. Together, this work not only provides an appropriate platform for waste biomass conversion, but also offers a new idea for expanding the application of integrating bio-GO and AOPs to remove antibiotics from water.