• 文献标题:   Achieving a thermally stable Eu2+-doped Sr2Si5N8 phosphor via adjusting the lattice defects of oxygen atoms and protection by the graphene-like multilayer
  • 文献类型:   Article
  • 作  者:   YANG X, XING XJ, ZHAO YJ, YANG ZY, LIU YF, MU CH, BUI HV, ZHANG ZW, AGATHOPOULOS S, XU X, YIN LJ
  • 作者关键词:   carbon coating, carbothermal reaction, thermal degradation, oxygen defect
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.ceramint.2023.03.139 EA MAY 2023
  • 出版年:   2023

▎ 摘  要

Sr2Si5N8:Eu2+ (258) phosphor has attracted much attention due to its excellent red emission properties. How-ever, its poor thermal stability hinders its further development in electronic display devices. Therefore, it is important to solve this problem in order to produce stable and long life-time WLED devices. In this work, a 258 phosphor was synthesized by a simple solid-phase reaction method, which was then coated by an ultrathin carbon layer by chemical vapor deposition. The carbon-coated powders were further annealed in N2 atmosphere at a high temperature to trigger the carbothermal reaction. On the one hand, the carbothermal reaction resulted in the removal of oxygen in the phosphor particle by a part of the carbon on the surface, which reduced the oxidation of both the luminescent centers and the host lattice. On the other hand, the remaining carbon crys-tallized, forming a graphene-like multilayer that protected the phosphor particle from the penetration of the external oxygen. This eventually resulted in a significant improvement of the thermal stability and oxidation resistance of the phosphor.