• 文献标题:   Reduced graphene oxide decorated Pt activated SnO2 nanoparticles for enhancing methanol sensing performance
  • 文献类型:   Article
  • 作  者:   PENG RQ, CHEN JH, NIE XK, LI DP, SI PC, FENG JK, ZHANG L, CI LJ
  • 作者关键词:   reduced graphene oxide, ptactivated sno2, gas sensor, mechanism
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Shandong Univ
  • 被引频次:   8
  • DOI:   10.1016/j.jallcom.2018.05.177
  • 出版年:   2018

▎ 摘  要

Methanol gas sensors with excellent performances are in great demand to monitor the industrial manufacture and many household products. We have synthesized Pt-activated SnO2 nanoparticles partly wrapped by reduced graphene oxide (RGO) for high performance methanol gas sensor application. The X-ray diffraction (XRD) and transmission electron microscopy (TEM) results indicated that the platinum element is present in two types, including metal (Pt) and tetravalent metal oxide (PtO2) in the Pt-activated SnO2 clusters. The SnO2 nanoparticles with an average size of about 10 nm are in form of cluster type and there are abundant random wormhole-like pores throughout each cluster. The gas responses of the pristine SnO2 gas sensor, Pt-activated SnO2 gas sensor and the RGO-assisted sensors toward 40 ppm methanol at the relatively low operating temperatures (110 degrees C) were 7.8, 38.5 and 60.1, respectively. And the sensor exhibited shorter response time with only 6 s. The excellent gas-sensing properties are mainly attributed to the improved electronic interaction and the reduced potential barrier between RGO and Pt/SnO2. (C) 2018 Elsevier B.V. All rights reserved.