• 文献标题:   Investigation of graphene oxide nanogel and carbon nanorods as electrode for electrochemical supercapacitor
  • 文献类型:   Article
  • 作  者:   OYEDOTUN KO, MADITO MJ, BELLO A, MOMODU DY, MIRGHNI AA, MANYALA N
  • 作者关键词:   grapheneoxide, reflux, gel, nanorod, specific capacitance/capacity, supercapacitor, energy storage
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Univ Pretoria
  • 被引频次:   18
  • DOI:   10.1016/j.electacta.2017.05.150
  • 出版年:   2017

▎ 摘  要

In this study, a gel of graphene oxide (GO) and carbon nanorods obtained from the GO gel were synthesized via a modified Hummers method and a force-driven reflux process respectively. Scanning electron microscopy (SEM) was used to analyse the morphology of the as-synthesized materials showing gelatinous and nanorods structures for the graphene oxide and carbon materials respectively. X-ray diffraction (XRD) suggests that the synthesized materials have a hexagonal crystal structure and an increased interlayer spacing due to the interlaced molecules of oxygen-containing functional groups. X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray spectroscopy (EDX) analysis were employed to confirm the presence of carbon and oxygen functionalities in the synthesized materials. Electrodes fabricated from both materials prove a limit specific capacitance of 436.5 F g(-1) and 719.5 F g(-1) corresponding to specific capacities of 48.5 mAh g-1 and 80.8 mAh g(-1) at a current density of 0.5 A g(-1) in a three electrode system with 6 M KOH electrolyte for both the graphene oxide gel and carbon nanorods respectively. The materials show good cycle stability after 3000 cycling at a current density of 5 Ag-1, which implies a great promise as electrodes for supercapacitor applications. (C) 2017 Elsevier Ltd. All rights reserved.