• 文献标题:   Graphene enhanced LiFeBO3/C composites as cathodes for Li-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHANG DY, QIAO J, DONG XX, XU BY, LI RF, CHANG CK
  • 作者关键词:   liion battery, cathode, lifebo3, graphene, conductive additive
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Shanghai Inst Technol
  • 被引频次:   3
  • DOI:   10.20964/2018.02.52
  • 出版年:   2018

▎ 摘  要

Graphene enhanced LiFeBO3/C composite electrodes are synthesized by a solid-state reaction. The effects of a graphene conductive additive on the LiFeBO3/C electrodes are characterized by XRD, SEM and electrochemical tests. The results show that the electronic conductivities of the LiFeBO3/C electrodes increase with increasing graphene content. The electronic conductivities of the LiFeBO3/C electrodes with Super P (SP) and 5% graphene (5%GN+SP) are 5.16x10(-3) S/cm and 1.65x10(-2) S/cm, respectively. The lithium ion diffusion coefficient (Du) of the LiFeBO3/C electrode with 3% graphene (3%GN+SP) is the highest at 9.85x10(-14) cm(2) s(-1), which is much higher than that of the SP electrode (5.94x10(-14) cm(2) s(-1)). The 3%GN+SP electrode has the highest capacity of 189.6 mAh/g at 0.1 C, and its cyclic retention is 95% after 50 cycles at 1 C. The performance enhancement is mainly attributed to the moderate addition of the graphene conductor, which could improve both the electronic conductivity and ionic diffusion coefficient of the LiFeBO3/C.