• 文献标题:   Nano LiFePO4 in reduced graphene oxide framework for efficient high-rate lithium storage
  • 文献类型:   Article
  • 作  者:   MUN J, HA HW, CHOI W
  • 作者关键词:   reduced graphene oxide, lithiumion batterie, cathode material, lithium iron phosphate, sol gel method
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Korea Inst Sci Technol
  • 被引频次:   42
  • DOI:   10.1016/j.jpowsour.2013.11.034
  • 出版年:   2014

▎ 摘  要

In this paper, we report a simple sol-gel method for the synthesis of a composite containing reduced graphene oxide (R-GO) embedded within nano LiFePO4 particles for a lithium-ion battery cathode. This composite has an effective electron pathway and a highly meso-porous structure as compared to conventional LiFePO4. Highly conductive R-GO, together with the meso-porosity results in a material that has good electronic conductivity and high electrolyte permeability. Electrodes fabricated from the composite exhibited excellent performance when evaluated as lithium-ion battery cathodes, including compared to pristine LiFePO4. The electrode of the R-GO composite exhibits excellent rate capabilities of 125 mAh g(-1) at 10 C, whereas pristine LiFePO4 could deliver only 81.5 mAh g(-1) at the same condition. It also achieves an improved cyclability with capacity retention ratios of 92.48% after 200 cycles at 10 C, as well. (C) 2013 Elsevier B.V. All rights reserved.