• 文献标题:   Greenly synthesized graphene with L-glutathione-modified electrode and its application towards determination of rutin
  • 文献类型:   Article
  • 作  者:   GAO YD, WANG L, ZHANG YL, LI S, ZOU LN, YE BX
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Zhengzhou Univ
  • 被引频次:   12
  • DOI:   10.1039/c6ra13457b
  • 出版年:   2016

▎ 摘  要

A simple, environmentally friendly and cost-effective approach for preparation of water-soluble functional graphene was proposed for constructing a voltammetric sensor platform. It was characterized by several techniques, including UV-vis spectroscopy, Fourier transform infrared spectroscopy, transmission electron microscopy (TEM) and X-ray diffraction (XRD). This voltammetric sensor showed strong accumulation ability and excellent voltammetric response for rutin. The electrochemical behavior of rutin was investigated systematically in 0.1 mol L-1 phosphate buffer solution (PBS 3.0). Under optimum conditions by square wave voltammetry (SWV), a good linear relationship was obtained between peak currents and rutin concentrations in the wider range of 5 x 10(-9) to 1 x 10(-6) mol L-1 with a detection limit of 7 x 10 (10) mol L (1). In addition, the proposed rutin sensor was successfully applied to test in real samples with good results.