• 文献标题:   VO2 (A)/graphene nanostructure: Stand up to Na ion intercalation/deintercalation for enhanced electrochemical performance as a Na-ion battery cathode
  • 文献类型:   Article
  • 作  者:   HU XY, ZHAO ZJ, WANG L, LI JB, WANG CZ, ZHAO YJ, JIN HB
  • 作者关键词:   naion battery, vo2 a nanowire, vo2 a /graphene composite, battery cathode material, cycle stability
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Beijing Inst Technol
  • 被引频次:   5
  • DOI:   10.1016/j.electacta.2018.10.010
  • 出版年:   2019

▎ 摘  要

Intercalation/deintercalation of large size Na ion leads to serious electrode materials fragmentation that would be the main reason of Na-ion battery capacity fading. Herein, we reported a Na-ion battery cathode material composed of layer-structured VO2 (A) nanowires wrapped with graphene. The VO2 (A)/graphene nanostructure which effectively suppressed pulverization of VO2 (A) nanowires during cyclic charging and discharging exhibited prominent cycle stability and high specific capacity. A reversible capacity of 115 mA h g(-1) was retained over 100 cycles at a high current density of 100 mA g(-1). Comparing to the electrochemical performance of other vanadium oxides, VO2 (A)/graphene demonstrates a potential cathode material for Na-ion batteries. (c) 2018 Elsevier Ltd. All rights reserved.