• 文献标题:   Graphene Oxide of Extra High Oxidation: A Wafer for Loading Guest Molecules
  • 文献类型:   Article
  • 作  者:   ABDELHALIM AOE, SHAROYKO VV, AGEEV SV, FARAFONOV VS, NERUKH DA, POSTNOV VN, PETROV AV, SEMENOV KN
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY LETTERS
  • ISSN:   1948-7185
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1021/acs.jpclett.1c02766 EA OCT 2021
  • 出版年:   2021

▎ 摘  要

We present a new modification of graphene oxide with very high content (85 wt %) of oxygen-containing functional groups (hydroxy, epoxy, lactol, carboxyl, and carbonyl groups) that forms stable aqueous dispersion in up to 9 g.L-1 concentration solutions. A novel faster method of the synthesis is described that produces up to 1 kg of the material and allows controlling the particle size in solution. The synthesized compound was characterized by various physicochemical methods and molecular dynamics modeling, revealing a unique structure in the form of a multilayered wafer of several sheets thick, where each sheet is highly corrugated. The ragged structure of the sheets forms pockets with hindered mobility of water that leads to the possibility of trapping guest molecules.