• 文献标题:   Novel electrochemical non-enzymatic glucose sensor based on 3D Au@Pt core-shell nanoparticles decorated graphene oxide/multi-walled carbon nanotubes composite
  • 文献类型:   Article
  • 作  者:   WANG RR, LIU XR, ZHAO YW, QIN JH, XU H, DONG LN, GAO SM, ZHONG LL
  • 作者关键词:   go/mwcnt mixture, au@pt np, nonenzymatic glucose sensing, synergistic effect
  • 出版物名称:   MICROCHEMICAL JOURNAL
  • ISSN:   0026-265X EI 1095-9149
  • 通讯作者地址:  
  • 被引频次:   12
  • DOI:   10.1016/j.microc.2021.107061 EA DEC 2021
  • 出版年:   2022

▎ 摘  要

A novel carbon composite was integrated with Au@Pt core-shell nanoparticles (Au@Pt NPs) to construct a sensing interface for enzyme-free electrochemical detection of glucose. As surfactant, graphene oxide (GO) was used to disperse multi-walled carbon nanotubes (MWCNTs). After the glassy carbon electrode (GCE) was modified with the mixture of GO and MWCNTs, the Au@Pt NPs were decorated on it. The prepared novel three-dimensional sensor interface was applied to detect glucose without enzyme at a remarkable negative potential (at about -0.013 V vs. Ag/AgCl), demonstrating a low detection limit (4.2 x 10(-8) M) and two wide linear range from 5 x 10(-8) to 1 x 10(-4) M and 1 x 10(-4) M to 2.5 x 10(-3) M. In addition, the non-enzymatic glucose sensing platform can be realized for practical application.