• 文献标题:   Sulfur-doped graphene promoted Li4Ti5O12@C nanocrystals for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   HUANG Z, LUO PF, ZHENG HH, LYU ZC
  • 作者关键词:   li4ti5o12@c, sulfurdoped graphene, lithiumion batterie, anode, highrate capability
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:  
  • 被引频次:   42
  • DOI:   10.1016/j.jallcom.2022.164599 EA MAR 2022
  • 出版年:   2022

▎ 摘  要

Herein, sulfur-doped graphene modified Li4Ti5O12@C nanocomposite (SG-T@C) has been firstly fabricated via a sol-gel method assisted with solid-state route. In this composite, the Li4Ti5O12@C nanocrystals (T@C) are homogeneously dispersed into the two-dimensional sulfur-doped graphene. The introduced sulfur-doped graphene acted as conductive bridge within the resulted nanocomposite, thereby enhancing the electrical conductivity of T@C nanoparticles. The as-fabricated SG-T@C displays superior high-rate perfor-mance for lithium-ion batteries. It can deliver the capacities of 171.9 and 145.2 mAh/g at 0.1 and 10 degrees C respectively. Besides, SG-T@C exhibits 96.2% capacity retention at 20 degrees C over 800 cycles, demonstrating an excellent cycling stability. Therefore, the designed SG-T@C can be used as an advanced electrode for li-thium-ion batteries. (c) 2022 Elsevier B.V. All rights reserved.