• 文献标题:   Co0.85Se on three-dimensional hierarchical porous graphene-like carbon for highly effective oxygen evolution reaction
  • 文献类型:   Article
  • 作  者:   ZHONG QS, XIA WY, LIU BC, XU CW, LI N
  • 作者关键词:   water splitting, oxygen evolution, co selenide, co0.85se, graphene
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Guangzhou Univ
  • 被引频次:   8
  • DOI:   10.1016/j.ijhydene.2019.03.003
  • 出版年:   2019

▎ 摘  要

Designing an efficient, cheap and abundant catalyst for oxygen evolution reaction (OER) is crucial for the development of sustainable energy sources. A novel catalyst which could be a promising candidate for such electrocatalysts is described. Co0.85Se supported on three-dimensional hierarchical porous graphene-like carbon (HPG) exhibits outstanding catalytic performances for OER in alkaline medium. It is found that the onset overpotential is 311 mV on the Co0.85Se/HPG electrode, which is more 28 and 41 mV negative than that on the Co/HPG and Co3O4/HPG electrodes. What's more, the value of Tafel slope is 61.7 mV dec(-1) and the overpotential at the current density of 10 mA cm(-2) is 385 mV on this electrode. The Co0.85Se/HPG of this work is an appealing electrocatalyst for OER in basic electrolyte. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.