• 文献标题:   A nitrogen and sulfur co-doped graphene-supported nickel tetrapyridyloxyphthalocyanine hybrid fabricated by a solvothermal method and its application for the detection of bisphenol A
  • 文献类型:   Article
  • 作  者:   ZHANG BW, WANG YS, DAI XH, LIU DJ, HE XQ
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Changchun Univ Sci Technol
  • 被引频次:   6
  • DOI:   10.1039/c5ra14516c
  • 出版年:   2015

▎ 摘  要

A novel hybrid consisting of nitrogen/sulfur co-doped graphene (N-S-G) and nickel tetrapyridyloxyphthalocyanine (NiTPPc) was fabricated by a solvothermal method and used for the voltammetric determination of bisphenol A (BPA). Compared with either pristine NiTPPc or N-S-G, the composite exhibits superior electrocatalytic activity towards the oxidation of BPA. Its oxidation peak current shows a linear dependence over the BPA concentration in the range from 0.2 to 122 mu M, with a detection limit of 25.5 nM (S/N = 3). Furthermore, the fabricated NiTPPc/N-S-G sensor has been applied for the determination of BPA in commercial plastic samples.