▎ 摘　　要

As the demand for wearable and foldable electronic devices increases rapidly, ultrathin and flexible thermal conducting films with exceptional electromagnetic interference (EMI) shielding effectiveness (SE) are greatly needed. Large-sized graphene oxide flakes and thermal treatment were employed to fabricate lightweight, flexible and highly conductive graphene films. Compared to graphene films made of smaller-sized flakes, the graphene film made of large-sized flakes possesses less defects and more conjugated domains, leading to higher electrical and higher thermal conductivities, as well as higher EMI SE. By compressing four-layer porous graphene films together, a 14 mm-thick graphene film (LG-4) was obtained, possessing EMI SE of 73.7 dB and the specific SE divided by thickness (SSE/t) of 25 680 dB cm(2) g(-1). The ultrahigh EMI shielding property of the LG-4 film originates from the excellent electrical conductivity (6740 S cm(-1)), as well as multi-layer structure composed of graphene laminates and insulated air pores. Moreover, the LG-4 film shows excellent flexibility and high thermal conductivity (803.1 W m(-1) K-1), indicating that the film is a promising candidate for lightweight, flexible thermal conducting film with exceptional EMI shielding performance.